Lamellar Reactions of Graphite with Aluminum Halides

ON THE REACTIONS IN ILMENITE, ALUMINUM AND GRAPHITE SYSTEM

Al2O3/TiC composites are used as cutting tools for machining gray cast iron and steels. The addition of iron improves the toughness of Al2O3/TiC composites. Ilmenite, aluminum and graphite can be used to produce in-situ Al2O3/TiC–Fe composites. However, the formation mechanism and reaction sequences of this system are not clear enough. Therefore, the present research is designed to determ...

Dielectric measurements of adsorbed krypton on lamellar halides

2014 We present simultaneous measurements of adsorption isotherms and dielectric isotherms for krypton on lamellar halides. The comparison between the two isotherms shows that dielectric method is well adapted to characterize the multilayer formation. The evolution of dielectric properties from a two-dimensional system towards the bulk is also obtained. J. Physique 42 (1981) 559-564 AVRIL 1981,

Burnishing of Aluminum-Magnesium-Graphite Composites

Ternary Intercalation Compound of Graphite with Aluminum Fluoride and Fluorine

A ternary intercalation compound of graphite with AIF3 and F2, CXF(A1F3)J/ was prepared under fluorine atmosphere at temperatures of 20-400 °C. The typical 1st stage compound has a composition of C6F(AlF3)o,i5 with a repeat distance of 940 pm. Rapid progress in the reaction led of the formation of graphite fluoride, (C2F),,. ESCA spectra indicate that the chemical bond between host graphite and...

Reactions of Amino-imino-boranes with Transition Metal Halides and Substituted Transition Metal Halides

The aminoiminoborane tmp-B=NCMe3 (1) adds to TiBr4 or ZrCL in a 1:1 ratio while PdCh adds 1 in a 1:2 ratio. In these new compounds the NBN unit is almost linear and the configuration corresponds to an allene. On the other hand 1 and Ti(OR)4 compounds and Ti(NMe2)4 give N metallated diaminoboranes tmp-B(X)-NCMe3EX3 (X = OR, NMe2). Mixed compounds Ti(OR)3_„X„ lead to diaminoboranes with BOR group...